書誌事項
- タイトル別名
-
- Oxidative Coupling of Methane over Samarium Oxide Doped with Alkali Fluorides.
抄録
Since samarium oxide has been reported as a catalyst capable of high methane conversion for oxidative coupling of methane, samarium oxides modified by doping with lithium-, sodium-, and potassium-fluorides were prepared for improving the selectivities for ethylene and ethane (referred to as C2-selectivity) and catalytic durability. The samarium oxides modified by doping with any alkali fluoride showed high C2-selectivity. The oxides modified with lithium fluoride gave high methane conversion and C2-selectivity especially, giving the highest yield of ethylene and ethane (referred to as C2-yield) of 27.8%, which was greater than that being considered as a limiting C2-yield (<25%) for oxidative coupling of methane.<br>The catalytic activity of the modified samarium oxides with lithium fluoride prepared by the impregnation method decreased after 80h of reaction. The deactivation was due to the vaporization of lithium fluoride from the catalyst surface and to the transformation of the crystal structure of samarium oxide from cubic to monoclinic. On the other hand, the modified catalyst prepared by sol-gel method showed a high catalytic durability capable of maintaining a high C2-yield (>21.6%) for more than 500h on stream. The lithium fluoride highly dispersed in the bulk of this catalyst must have diffused to the surface to make up for the lost lithium fluoride therefrom during reaction.
収録刊行物
-
- 石油学会誌
-
石油学会誌 40 (2), 65-70, 1997
公益社団法人 石油学会
- Tweet
キーワード
詳細情報 詳細情報について
-
- CRID
- 1390282681272232960
-
- NII論文ID
- 130003584141
-
- ISSN
- 05824664
-
- 本文言語コード
- ja
-
- データソース種別
-
- JaLC
- Crossref
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可