The Effect of Geometry on Electronic Properties of Transition Metal Compounds

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  • 幾何学的効果が誘起する遷移金属化合物の電子系の異常
  • キカガクテキ コウカ ガ ユウキ スル センイ キンゾク カゴウブツ ノ デンシケイ ノ イジョウ

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The effect of geometry, particularly, geometric frustration on electronic properties of itinerant electron magnets are discussed. As an example, the competition between intra- and inter-dimer interaction, and the characteristic lattice dynamics in Mo3Sb7 are briefly reviewed. A new possible and promising candidate of the metallic frustrated lattice, the stella quadrangula lattice, found in compounds with the η-carbide type structure, etc., is introduced.

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