Production of MgB2 Superconducting Material by Combustion Synthesis with Heat of Formation of Ti and C.

DOI 1 Citations 11 References

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Other Title
  • ＴｉとＣの生成熱を利用したＭｇＢ２超電導体の燃焼合成法による製造
  • Ti ト C ノ セイセイ ネツ オ リヨウ シタ MgB2 チョウデンドウタイ ノ ネンショウ ゴウセイホウ ニ ヨル セイゾウ

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Abstract

It is revealed recently that the familiar chemical compound MgB2 is a superconducting material and the superconducting transition temperature Tc is 39 K It is not easy to produce the good MgB2 by conventional production method. The simple method to produce the MgB2 in a short time is developed by means of a combustion synthesis process with the heat of formation of elements. MgB2 is not able to be produced by a direct combustion synthesis process of Mg and B. Some main reasons are that the heat of formation of MgB2 is small, Mg tends to vaporize, and the Mg powder is very rough but B powder is very fine. On the other hand, MgB2 is able to be produced by the combustion synthesis process of Mg and B using the combustion synthesis of Ti and C proposed in the present paper. The oxidation and the vaporization of Mg are suppressed because the production is done in a very short time in a high vacuum. Moreover, the ratio of Mg and B is stabilized, so that the superconducting properties are assumed to be improved and the production process of MgB2 becomes simple.

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Details

  • CRID
    1390282681285841920
  • NII Article ID
    10009579589
  • NII Book ID
    AN00222724
  • DOI
    10.2497/jjspm.49.588
  • ISSN
    18809014
    05328799
  • NDL BIB ID
    6227701
  • Text Lang
    ja
  • Data Source
    • JaLC
    • NDL
    • Crossref
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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