書誌事項
- タイトル別名
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- Interpretation of Superconductivity and its Critical Temperature (Tc) in Elemental Substances by Valence Electron Parameters
- ゲンソ ブッシツ ニ オケル チョウデンドウ ハツゲン ト リンカイ オンド Tc ノ カデンシ パラメーター ニ ヨル カイシャク
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説明
It has been tried to interpret the superconductivity and its critical temperature (Tc ) in the elemental substances by the orbital electronegativity of the s electron, (Z/r (s))1/2, which is defined by the pseudopotential radius of the s electron, r (s), and the valence, Z. Dependence of critical temperature (Tc ) on (Z/r (s))1/2 showed a convex curve with a maximum around (Z/r (s))1/2=2.0, except for several substances and it is found that the elemental substances with higher Tc such as Nb and Pb have a (Z/r (s) )1/2 value close to the threshold one corresponding to the change from metal to semiconductor. Many exceptional substances can be plotted close to the convex curve by considering the effect of the p electron or by changing the cohesion state from bulk to film, suggesting the increase of Tc value due to the increase of s- and/or p-characters, though the critical temperature for metastable elemental substances is not completely explained by the orbital electronegativity of the s electron.
収録刊行物
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- 粉体および粉末冶金
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粉体および粉末冶金 58 (7), 412-416, 2011
一般社団法人 粉体粉末冶金協会
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詳細情報 詳細情報について
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- CRID
- 1390282681286829440
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- NII論文ID
- 10029437833
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- NII書誌ID
- AN00222724
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- COI
- 1:CAS:528:DC%2BC3MXhtVGiu7nL
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- ISSN
- 18809014
- 05328799
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- NDL書誌ID
- 11189017
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
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- 使用不可