The Effect of Transition Element Doping on the Particulate Matter Oxidation of La<sub>1.5</sub>Sr<sub>1.5</sub>Mn<sub>2</sub>O<sub>7−</sub><i><sub>σ</sub></i>

  • KATO Ippei
    Tokyo City University, Faculty of Engineering, Department of Chemistry and Energy Engineering, and Advanced Research Laboratories,
  • MORIYA Masaki
    Tokyo City University, Faculty of Engineering, Department of Chemistry and Energy Engineering, and Advanced Research Laboratories,
  • IKEDA Tetsuya
    Tokyo City University, Faculty of Engineering, Department of Chemistry and Energy Engineering, and Advanced Research Laboratories,
  • MASUDA Kohji
    Nissan Research Center, Nissan Motor Co., Ltd.
  • MUNAKATA Fumio
    Tokyo City University, Faculty of Engineering, Department of Chemistry and Energy Engineering, and Advanced Research Laboratories,

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Other Title
  • La<sub>1.5</sub>Sr<sub>1.5</sub>Mn<sub>2</sub>O<sub>7−</sub><i><sub>σ</sub></i>の粒子状物質酸化に及ぼす遷移金属元素置換の効果
  • La₁.₅Sr₁.₅Mn₂O₇-σの粒子状物質酸化に及ぼす遷移金属元素置換の効果
  • La ₁.₅ Sr ₁.₅ Mn ₂ O ₇-s ノ リュウシジョウ ブッシツ サンカ ニ オヨボス センイ キンゾク ゲンソ チカン ノ コウカ
  • The Effect of Transition Element Doping on the Particulate Matter Oxidation of La1.5Sr1.5Mn2O7−σ

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Abstract

The effect of transition element (TE = Fe, Ni, Cu) doping on the particulate matter (PM) oxidation in the Ruddlesden-Popper-type (RP - type) compound La1.5Sr1.5Mn2O7−σ was investigated for a dopant concentration fixed of 0.05 %. Though there is no structural change accompanied by doping, thermogravimetry curves show the noticeable difference according to the dopant. Then, Cu doping is found to be more effective than Fe and Ni doping. Finally, it was found that La1.5Sr1.5Mn1.95Cu0.05O7−σ is one of the promising PM oxidation catalysts for the catalyzed soot filter.

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