薄肉ブレージングシートの耐食性に及ぼす心材へのＭｎ添加の効果

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  • Effect of Mn addition to core alloy on corrosion resistance of thin brazing sheet
  • ウスニク ブレージングシート ノ タイショクセイ ニ オヨボス シンザイ エ ノ Mn テンカ ノ コウカ

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抄録

To investigate effect of additional Mn in thin brazing sheet (core alloy) on corrosion resistance, SWAAT and electrochemical measurements have been carried out with brazed Al–Mn–1.6 mass%Si alloys. Intergranular corrosion clearly occured in the alloys which Mn content is 1 mass% or less. In the case of these alloys precipitates of Si particle were observed at grain boundary, but they were not observed in grain after brazing. As a result, the potential difference between neighborhood of the grain boundaries and grain matrix became bigger. Therefore, selective dissolution occured at neighborhood of the grain boundaries which was lower solid solution of Si. On the other hand, intergranular corrosion were not observed in the alloys which Mn content is 1.6 mass% or more. In the case of these alloys fine precipitates of AlMnSi were observed in grain after brazing. As a result, the formation of Si-SDZ (solute depleted zone) by Si precipitation at grain boundary seen in the former alloys were inhibited. In conclusion, addition of Mn in thin brazing sheet had improving effect of corrosion resistance after brazing.

収録刊行物

  • 軽金属

    軽金属 60 (7), 327-332, 2010

    一般社団法人 軽金属学会

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