Studies on the Liquefaction of Waste Expanded Polystyrene. Part II. Scale Effect on the Pyrolysis of Expanded Polystyrene in the Presence of 2,4-Diphenyl-4-methyl-1-pentene.

  • XUE Feng
    Department of Applied Chemistry, Faculty of Engineering, Utsunomiya University
  • KOBAYASHI Tomokazu
    Department of Applied Chemistry, Faculty of Engineering, Utsunomiya University
  • KIMURA Takao
    Department of Applied Chemistry, Faculty of Engineering, Utsunomiya University
  • MINABE Masahiro
    Department of Applied Chemistry, Faculty of Engineering, Utsunomiya University
  • NAKAJIMA Michihiro
    Department of Agricultural Environmental Engineering, Faculty of Agriculture, Utsunomiya University
  • KASHIWAZAKI Masaru
    Research Farm, Faculty of Agriculture, Utsunomiya University

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Other Title
  • 廃棄発泡スチロールの油化還元に関する研究 第2報  2,4‐ジフェニル‐4‐メチル‐1‐ペンテン共存系での発泡スチロールの熱分解におけるスケール効果
  • 2 4 ジフェニル 4 メチル 1 ペンテン キョウゾンケイ デ ノ ハッポウ スチロール ノ ネツ ブンカイ ニ オケル スケール コウカ
  • Studies on the Liquefaction of Waste Expanded Polystyrene Part II
  • 廃棄発泡スチロールの油化還元に関する研究(第2報)

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Abstract

The pyrolysis of expanded polystyrene (EPS) with 2, 4-diphenyl-4-methyl-1-pentene (MSD) as an additive was studied at a temperature about 200°C. In the time, the scale of EPS was increased in steps from 0.25g to 10g. We found that it was important to control the temperature in the reaction vessel because the temperature gradient of gas-phase and liquid-phase enlarged with an increase in the scale of EPS, and it was also necessary to remove the residual oxygen in the reaction vessel during the pyrolysis. The most efficient molar ratio of MSD to EPS decreased with an increase in the scale of EPS, but the absolute weight of MSD did not change.

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