Real-Space Investigation of Intermolecular Energy Transfer by Scanning Tunneling Luminescence Spectroscopy
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- IMADA Hiroshi
- RIKEN
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- MIWA Kuniyuki
- RIKEN
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- IMAI-IMADA Miyabi
- RIKEN The University of Tokyo
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- KAWAHARA Shota
- RIKEN The University of Tokyo
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- KIMURA Kensuke
- RIKEN The University of Tokyo
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- KIM Yousoo
- RIKEN
Bibliographic Information
- Other Title
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- 走査トンネル顕微鏡発光分光法による分子間エネルギー移動の実空間計測
- ソウサ トンネル ケンビキョウ ハッコウ ブンコウホウ ニ ヨル ブンシ カン エネルギー イドウ ノ ジツ クウカン ケイソク
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Abstract
<p>Energy transfer is an essential process in photosynthesis and various energy-harvesting devices. So far, nanoscale features of energy transfers are unknown because of the limited spatial resolution of conventional methods. We conducted a molecular-level investigation of energy transfers in molecular dimers consisting of a free-base phthalocyanine and magnesium phthalocyanine (H2Pc and MgPc) by scanning tunneling luminescence spectroscopy. Local excitation of an MgPc with the tunneling current of a scanning tunneling microscope give rise to luminescence from a nearby H2Pc as a result of energy transfer. We demonstrate the possibility of a single-molecule valve device for energy transfer, which is revealed by a blinking behavior of energy transfer. Moreover, a back-and-forth energy transfer was observed, where the energy was transferred from the second singlet state (so-called Qy state) of H2Pc to the first singlet state (Q state) of MgPc and finally to the first singlet state (Qx state) of H2Pc.</p>
Journal
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- Hyomen Kagaku
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Hyomen Kagaku 38 (9), 455-459, 2017
The Surface Science Society of Japan
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Details 詳細情報について
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- CRID
- 1390282681436120832
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- NII Article ID
- 130006083392
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- NII Book ID
- AN00334149
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- ISSN
- 18814743
- 03885321
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- NDL BIB ID
- 028529343
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- Text Lang
- ja
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- Data Source
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- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
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- Abstract License Flag
- Disallowed