Synthesis and Toxicity of Allethrin-(Z)-metabolites

DOI DOI オープンアクセス
  • SUGIYAMA Takeyoshi
    Department of Agricultural Chemistry, Faculty of Agriculture, Tohoku University
  • KOBAYASHI Akio
    Department of Agricultural Chemistry, Faculty of Agriculture, Tohoku University
  • YAMASHITA Kyohei
    Department of Agricultural Chemistry, Faculty of Agriculture, Tohoku University
  • SUZUKI Takashi
    Research Department, Pesticides Division, Takarazuka Research Laboratory, Sumitomo Chemical Co., Ltd.

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説明

(±)-trans-Allethrin-(Z)-ol (IV), (±)-trans-allethrin-(Z)-al (V) and (±)-trans-allethrin-(Z)-<br>acid (VI), the minor components of allethrin metabolites in the insect body, were synthesized. The toxicities of newly synthesized allethrin derivatives (IV, V, VI) and of (±)-trans-allethrin-(E)-acid (Xc) to houseflies (Musca domestica L.) were examined by the injection method. And <br>their low toxicities seem to support the hypothesis that oxidation at the isobutenyl side chain <br>of the acid moiety of the allethrin molecule is a detoxication process in the insect body.

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詳細情報 詳細情報について

  • CRID
    1390282681446205952
  • NII論文ID
    130003415583
  • DOI
    10.1271/bbb1961.36.2275
    10.1080/00021369.1972.10860556
  • COI
    1:CAS:528:DyaE3sXhtFSltro%3D
  • ISSN
    18811280
    00021369
  • 本文言語コード
    en
  • データソース種別
    • JaLC
    • Crossref
    • CiNii Articles
    • OpenAIRE
  • 抄録ライセンスフラグ
    使用不可

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