The Reaction of Enamines with N-Dialkylchloramines

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The reaction of dialkylchloramines with N-dialkyl-substituted aminoisobutenes was shown to give a mixture of the two α-dialkylaminoaldehydes, which were derived not only from the addition of chloramine, but also from the rearrangement of amino group in the parent enamines. The results suggested an ionic path involving _??_ cyclic dialkylaziridiniurn ion as intermediate. The possible mechanism of these reactions was discussed.

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Details 詳細情報について

  • CRID
    1390282681446601472
  • NII Article ID
    130003523934
  • DOI
    10.1271/bbb1961.36.799
    10.1080/00021369.1972.10860313
  • COI
    1:CAS:528:DyaE38XktlektLc%3D
  • ISSN
    18811280
    00021369
  • Text Lang
    en
  • Data Source
    • JaLC
    • Crossref
    • CiNii Articles
    • OpenAIRE
  • Abstract License Flag
    Disallowed

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