Resolution and Synthesis of (S)-1-(2-Naphthyl)ethanol with Immobilized Pea Protein: As a New Biocatalyst.

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  • NAGAOKA Hiroyuki
    The United Graduate School of Agricultural Science, Gufu University Sanyo Shokuhin Co., Ltd.
  • KAYAHARA Hiroshi
    Department of Bioscience and Biotechnology, Shinshu University

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  • Resolution and Synthesis of (<i>S</i>)-1-(2-Naphthyl)ethanol with Immobilized Pea Protein: As a New Biocatalyst

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  (S)-1-(2-Naphthyl)ethanol was yielded by immobilized pea (Pisum sativum L.) protein (IPP) from (R, S) 2-naphthyl ethanol (>99% ee, yield; about 50%), in which the (R)-enantiomer was selectively oxidized to 2-acetonaphthone. IPP could be reused consecutively at least three times without any decrease of yield and optical purity.<br>

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