Synthesis of Both Enantiomers of Isorobinal, a Novel Cyclic Monoterpene Isolated from the Astigmatid Mite, Rhizoglyphus sp.

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  • LIANG Ting
    <i>Laboratory of Applied Bioorganic Chemistry, Division of Life Science, Graduate School of Agricultural Science, Tohoku University</i>
  • KUWAHARA Shigefumi
    <i>Laboratory of Applied Bioorganic Chemistry, Division of Life Science, Graduate School of Agricultural Science, Tohoku University</i>

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  • Synthesis of Both Enantiomers of Isorobinal, a Novel Cyclic Monoterpene Isolated from the Astigmatid Mite,<i>Rhizoglyphus</i>sp.

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Abstract

  Both enantiomers of isorobinal, a cyclic monoterpene isolated from the astigmatid mite (Rhizoglyphus sp.), were synthesized from the enantiomers of perillaldehyde in four steps by using PCC-oxidation of a tertiary allylic alcohol intermediate as the key step.<br>

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