Identification of 2,3-Dihydro-γ-ionylideneethanol in Cercospora cruenta
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- YAMAMOTO Hirotaka
- Faculty of Agriculture, Niigata University
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- INOMATA Masahiro
- Faculty of Agriculture, Niigata University
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- UCHIYAMA Takeo
- Faculty of Agriculture, Niigata University
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- ORITANI Takayuki
- Graduate School of Agricultural Science, Tohoku University
書誌事項
- タイトル別名
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- Identification of 2,3-Dihydro-.GAMMA.-ionylideneethanol in Cercospora cruenta.
- Identification of 2 3 Dihydro ガンマ ionylideneethanol in Cercospora cruenta
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説明
During our scrutiny of GC-EI-MS date for C15 alcohols as putative intermediates on the ABA biosynthetic pathway in Cercospora cruenta, a trace amount of 5-[2',2'-dimenthyl-6'-methylene-1'-cyclohexyl]-3-methyl-4-penten-1-ol (2,3-dihydro-γ-ionylideneethanol) was identified. Feeding experiments indicated that this compound was not an intermediate to ABA, but a catabolite that originated from γ-ionylideneacetaldehyde. The stereochemistry of 2,3-dihydro-γ-ionylideneethanol was deduced to be (3R,1'S) from a comparison with an authentic specimen prepared via baker’s yeast asymmetric reduction.
収録刊行物
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- Ｂｉｏｓｃｉｅｎｃｅ， Ｂｉｏｔｅｃｈｎｏｌｏｇｙ， ａｎｄ Ｂｉｏｃｈｅｍｉｓｔｒｙ
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Ｂｉｏｓｃｉｅｎｃｅ， Ｂｉｏｔｅｃｈｎｏｌｏｇｙ， ａｎｄ Ｂｉｏｃｈｅｍｉｓｔｒｙ 65 (4), 810-816, 2001
公益社団法人 日本農芸化学会
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詳細情報 詳細情報について
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- CRID
- 1390282681452569600
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- NII論文ID
- 110002680349
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- NII書誌ID
- AA10824164
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- COI
- 1:CAS:528:DC%2BD3MXjsVagsLo%3D
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- ISSN
- 13476947
- 09168451
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- NDL書誌ID
- 5768825
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- PubMed
- 11388457
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- 本文言語コード
- en
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- 資料種別
- journal article
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- データソース種別
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- JaLC
- NDLサーチ
- Crossref
- PubMed
- CiNii Articles
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- 使用不可