Structure of Green Pigment Formed by the Reaction of Caffeic Acid Esters (or Chlorogenic acid) with a Primary Amino Compound.

DOI Web Site Web Site PubMed 被引用文献2件 参考文献25件
  • YABUTA Goro
    Department of Fermentation Science, Faculty of Applied Bioscience, Tokyo University of Agriculture
  • KOIZUMI Yukimichi
    Department of Fermentation Science, Faculty of Applied Bioscience, Tokyo University of Agriculture
  • NAMIKI Kazuko
    Department of Fermentation Science, Faculty of Applied Bioscience, Tokyo University of Agriculture Current address: Sugiyama Jogakuen University
  • HIDA Mitsuhiko
    Department of Fermentation Science, Faculty of Applied Bioscience, Tokyo University of Agriculture Current address: Tokyo Metropolitan University
  • NAMIKI Mitsuo
    Department of Fermentation Science, Faculty of Applied Bioscience, Tokyo University of Agriculture Current address: Nagoya University

この論文をさがす

抄録

A marked greening observed in some foods such as sweet potato, burdock, and others during food processing was shown to be due to green pigment formation by the condensation reaction of two molecules of chlorogenic acid or caffeic acid ester with one molecule of a primary amino compound under aeration in alkaline solution. Reduction of the green pigment by ascorbic acid or NaBH4 gave a yellow product, which readily turn green and then blue in air. The reduced and acetylated product of the green pigment was identified to be a novel trihydroxy benzacridine derivative, and the yellowish ethanol solution of this product immediately turned green upon addition of butyl amine or diluted alkali. Therefore, the green pigment was assumed to be an oxidized quinone type product of trihydroxy benzacridine. This identification of the structure was supported by the correspondence of the measured absorption spectra with those calculated by the molecular orbital method. A possible charge transfer complex between products of different oxidation steps in green solution was proposed.

収録刊行物

被引用文献 (2)*注記

もっと見る

参考文献 (25)*注記

もっと見る

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ