Asymmetric Trans-esterification of meso-2,5-Dibromoadipate and Synthesis of Optically Active cis-2,5-Disubstituted Pyrrolidines.

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  • Asymmetric Trans-esterification of<i>meso</i>-2,5-Dibromoadipate and Synthesis of Optically Active<i>cis-</i>2,5-Disubstituted Pyrrolidines

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Asymmetric trans-esterification of meso-2, 5-dibromoadipate to ( - )-benzyl methyl 2, 5-dibromoadipate by lipase with subsequent chemical reactions afforded optically active cis-2, 5-disubstituted pyrrolidines. An equivalent asymmetric transformation was performed by selectively hydrolyzing a cis-2, 5-disubstituted pyrrolidine having a chiral N-substituent.

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