書誌事項
- タイトル別名
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- High-Temperature Oxidation of Sintered .BETA.-FeSi2 Bodies at Elevated Temperatures
- 大気中におけるβ-FeSi2焼結体の高温酸化
- タイキ チュウ ニ オケル ベータ FeSi2 ショウケツタイ ノ コウオン サンカ
- High-Temperature Oxidation of Sintered β-FeSi2 Bodies at Elevated Temperatures
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抄録
β-FeSi2, which is one of the thermoelectric materials, has been more attractive in high-temperature range because of its low cost of raw materials. Oxidation resistance of sintered β-FeSi2 was investigated at temperatures ranging from 1073 to 1223 K in air. Fully densified and porous β-FeSi2 samples were fabricated by using the pulsed electric current sintering method. They were annealed at 1173 K for 5d to obtain β-FeSi2 phase. Microstructure of oxidized sample was observed by scanning electron microscopy with energy dispersion X-ray spectroscopy. Phase identification of samples oxidized was carried out by X-ray diffraction. Oxide layer, which is most likely an amorphous SiO2, was formed on β-FeSi2 samples after oxidation. Growth of the oxide layer obeyed a parabolic law. Growth rate of the oxide layer on sintered β-FeSi2 was comparable to that of Si. Granular ε-FeSi was developed below the oxide layer as a result of oxidation of β-FeSi2. Grain boundary oxidation was not observed. Formation of cracks in the SiO2 layer and β-FeSi2 was not observed even in on the porous samples. Oxidation resistance of sintered β-FeSi2 was excellent for high-temperature thermoelectric applications.<br>
収録刊行物
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- 日本金属学会誌
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日本金属学会誌 70 (1), 20-24, 2006
公益社団法人 日本金属学会
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詳細情報 詳細情報について
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- CRID
- 1390282681456744192
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- NII論文ID
- 10017152863
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- NII書誌ID
- AN00187860
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- ISSN
- 18806880
- 24337501
- 00214876
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- NDL書誌ID
- 7804620
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可