溶融銅の表面張力に及ぼす硫黄の影響

書誌事項

タイトル別名
  • Effect of Dissolved Sulphur on the Surface Tension of Liquid Copper (Fundamental Studies on Cermet, Part 4)
  • ヨウユウ ドウ ノ ヒョウメン チョウリョク ニ オヨボス イオウ ノ エイキョウ

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抄録

The effect of dissolved sulphur on the surface tension of liquid copper has been measured by the sessile drop method at 1114°, 1200°, 1300° and 1340°C. Sulphur is highly “surface active” in liquid copper, and at a sulphur content of 0.6%, the surface tension is lowered by about 620 dyn·cm−1 at 1114°, 580 dyn·cm−1 at 1200°, 530 dyn·cm−1 at 1300° and 470 dyn·cm−1 at 1340°C, respectively. The degree of adsorption of sulphur on the liquid copper surface has been calculated and the result indicates that the maximum surface excess of sulphur is about 1.6×10−9 mol·cm−2, which corresponds to a mono-molecular layer of Cu2S or S−−.

収録刊行物

  • 日本金属学会誌

    日本金属学会誌 24 (6), 374-377, 1960

    公益社団法人 日本金属学会

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