Ni-W合金中のNi<SUP>63</SUP>およびW<SUP>185</SUP>の拡散

書誌事項

タイトル別名
  • Diffusion of Ni<SUP>63</SUP> and W<SUP>185</SUP> in Nickel-Tungsten Alloys (On the Relation between High-Temperature Creep and Diffusion in Nickel Base Solid Solutions. III)
  • Ni-W合金中のNi63およびW185の拡散
  • Ni-W ゴウキン チュウ ノ Ni63 オヨビ W185 ノ カクサン

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抄録

The self-diffusion coefficients of nickel and tungsten in nickel-tungsten alloys containing 0 to 9 at%W have been measured with a usual lathe sectioning technique. Polycrystalline specimens having 1 to 4 mm grain size were used. Measurements were carried out over the temperature range from about 1100° to 1400°C. In this system, nickel atom diffuses more rapidly than tungsten atom, and the ratio of diffusion coefficient of nickel to that of tungsten is from 3 to 4 for each composition over the temperature range examined. Diffusion rates of both elements decrease with increasing tungsten contents. The frequency factors for nickel self-diffusion are 1.9, 30, 58 and 1.1 cm2/sec, and the activation energies are 68.0, 76.5, 80.6 and 70.3 kcal/mol for alloys containing 0, 1.7, 5.3 and 9.2 at% tungsten, respectively. For tungsten self-diffusion in respective alloys, the frequency factors obtained are 2.0, 2.2, 17 and 1.4 cm2/sec, and the activation energies are 71.5, 73.1, 80.5 and 74.5 kcal/mol.

収録刊行物

  • 日本金属学会誌

    日本金属学会誌 28 (4), 197-200, 1964

    公益社団法人 日本金属学会

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