Se-Te系のクヌーセンセル・マスフィルタによる熱力学的解析

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タイトル別名
  • A Thermodynamic Study of the Se-Te System by the Knudsencell-Massfilter Method
  • Se Teケイ ノ クヌーセンセル マス フィルタ ニヨル ネツリキガクテキ
  • Thermodynamic study of the Se–Te system by the Knudsencell-Massfilter method

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Mass spectrometric analysis of the vapour phase of Se-Te alloys was performed by means of a mass filter. The heat of vaporization and activities of Se and Te were measured over the whole composition range. The activity data on Se and Te showed a positive deviation from Raoult’s law at 714 K. The highest departures were observed in the dilute solutions.<BR>The trimer, Te3, was detected over Te and Se-Te alloy melts. The vapour phase of Se-Te alloys was very complex to form Se, Se2, Te, SeTe, Se2Te, Se3, SeTe2, Se4, Te3, Se3Te, Se5, Se2Te2 and Se4Te within 500 amu.<BR>The inexpensive mass-filter was found to be serviceable for the study of the complex system.

収録刊行物

  • 日本金属学会誌

    日本金属学会誌 40 (9), 958-964, 1976

    公益社団法人 日本金属学会

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