書誌事項
- タイトル別名
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- Mechanism of the Gas-Phase Hydrogen/Deuterium Exchange Associated with Positive Ion Direct Analysis in Real Time (DART)
- DART セイ イオンカ ニ オケル キソウ H/D コウカン ハンノウ ノ ケンショウ
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説明
Gas-phase hydrogen/deuterium (H/D) exchange between D2O, CH3OD, CH3CH2OD, ND3 and ascorbic acid was examined, in an attempt to understand the mechanism responsible for the gas-phase ion/molecular reactions that occur in Direct Analysis in Real Time (DART)．Ionized water/ammonium clusters played an important role in the H/D exchange process, known as a transient microenvironment (TME)．Argon was used as an alternative DART gas to eliminate formation of ionized water clusters. These experiments clearly characterized the gas-phase H/D exchange process of positive-ion DART.
収録刊行物
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- 質量分析
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質量分析 62 (1), 1-4, 2014
一般社団法人 日本質量分析学会
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詳細情報 詳細情報について
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- CRID
- 1390282681472191232
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- NII論文ID
- 130003393085
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- NII書誌ID
- AN0010555X
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- COI
- 1:CAS:528:DC%2BC2cXps1WgtL4%3D
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- ISSN
- 18804225
- 18843271
- 13408097
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- NDL書誌ID
- 025196322
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可