Effects of CO2 concentration and electric current on the ionic conductivity of anion exchange membranes for fuel cells
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- KIMURA Takeshi
- Department of Innovative and Engineered Materials, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology
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- YAMAZAKI Yohtaro
- Department of Innovative and Engineered Materials, Interdisciplinary Graduate School of Science and Engineering, Tokyo Institute of Technology
書誌事項
- タイトル別名
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- Effects of CO<sub>2</sub> Concentration and Electric Current on the Ionic Conductivity of Anion Exchange Membranes for Fuel Cells
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The dependences of the CO2 concentration and the effects of electric current on the ionic conduction properties of anion exchange membranes (AEMs) in fuel cells were investigated. The ionic conductivity of AEMs was measured by AC impedance method at 40°C in various atmospheres. After the initial ion exchange process, contact with air containing 38% CO2 caused the ionic conductivity of AEMs to decrease to 40% of the value measured immediately after the initial ion exchange process. However, exposing the AEMs in a CO2-free air atmosphere increased the ionic conductivity to 50% of the value measured immediately after the initial ion exchange process. Then 89 C cm−2 of direct current (DC) was applied in a CO2-free atmosphere to the AEMs. The ionic conductivity increased close to the value measured immediately after the initial ion exchange process. These results are discussed by assuming that bicarbonate (HCO3−) is produced in the AEMs.
収録刊行物
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- Electrochemistry
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Electrochemistry 79 (2), 94-97, 2011
公益社団法人 電気化学会
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詳細情報 詳細情報について
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- CRID
- 1390282681472306048
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- NII論文ID
- 10027415695
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- NII書誌ID
- AN00151637
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- COI
- 1:CAS:528:DC%2BC3MXhvVGrsrc%3D
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- ISSN
- 21862451
- 13443542
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- NDL書誌ID
- 10958961
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用可