Cyclic Voltammetric Studies on Electrocatalytic Intermolecular [2 + 2] Cycloaddition Reactions in Lithium Perchlorate/Nitromethane Electrolyte Solution

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  • YAMAGUCHI Yusuke
    Department of Applied Biological Science, Tokyo University of Agriculture and Technology
  • OKADA Yohei
    Department of Applied Biological Science, Tokyo University of Agriculture and Technology
  • CHIBA Kazuhiro
    Department of Applied Biological Science, Tokyo University of Agriculture and Technology

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Abstract

Electrocatalytic reactions build targeted molecules with low energy consumption and thus are intriguing both synthetically and mechanistically. We have carried out cyclic voltammetric studies on electrocatalytic intermolecular [2 + 2] cycloaddition reactions between an enol ether and an olefin nucleophile to reveal the electron transfer reactions in detail at the surface of the electrode.

Journal

  • Electrochemistry

    Electrochemistry 81 (5), 331-333, 2013

    The Electrochemical Society of Japan

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