書誌事項
- タイトル別名
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- Fundamentals of Mass Spectrometry -Chemical Reaction by Core Electron Excitation-
- キソ カラ マナブ マススペクトロメトリー シツリョウ ブンセキ ノ ゲンリュウ ダイ5カイ ナイカクレイキハンノウ
- —Chemical Reaction by Core Electron Excitation—
- 第5回 内殻励起反応
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抄録
Core electron excitation possesses an attractive potential of inducing selective chemical bond breaking. Compared to valence excitation, core excitation takes place within a small area because of its spatial localization and atomic selectivity. Therefore, a specific atom in a molecule can be excited selectively. The core-excited state is quite unstable with an extremely high energy, so consecutive decay processes—Auger decay and ionic dissociation—can occur in the vicinity of the excited atom. From this concept, site-selective ionic fragmentation has been widely and successfully investigated in various core-excited molecular systems. This paper briefly describes the characteristics of core excitation and experimental methods, and then reviews representative recent studies about site-selective chemical bond breaking induced by core excitation.
収録刊行物
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- 質量分析
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質量分析 58 (1), 17-27, 2010
一般社団法人 日本質量分析学会
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詳細情報 詳細情報について
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- CRID
- 1390282681473554560
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- NII論文ID
- 10026278777
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- NII書誌ID
- AN0010555X
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- ISSN
- 18804225
- 18843271
- 13408097
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- NDL書誌ID
- 10563749
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
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- 抄録ライセンスフラグ
- 使用不可