Analysis of Insoluble Organic Pigments by Desorption/Ionization Mass Spectrometry
-
- ASAKAWA Daiki
- Clean Energy Research Center, University of Yamanashi
-
- KUDAKA Ichiro
- Mitsubishi Chemical Safety Institute Ltd.
-
- HIRAOKA Kenzo
- Clean Energy Research Center, University of Yamanashi
Bibliographic Information
- Other Title
-
- 脱離イオン化質量分析法による難溶性顔料の分析
- ダツリ イオンカ シツリョウ ブンセキホウ ニ ヨル ナンヨウセイ ガンリョウ ノ ブンセキ
Search this article
Description
We performed a comparison of electrospray droplet impact (EDI) with laser desorption ionization (LDI) and matrix-assisted laser desorption/ionization (MALDI) to analyze several organic pigments, including Pigment Yellow 93, Pigment Yellow 180, and Pigment Green 36, as test samples. These samples are poorly soluble in standard solvents. In EDI, samples were prepared by direct deposition of the powder samples on the substrates. No matrices were used. We also found that EDI was an easy, versatile method for testing as-received samples. However, some fragment ions were generated in the EDI process. In contrast, in negative-mode MALDI mass spectrometry using tetrathiafulvalene (TTF) as a matrix, we found that fragment ions were much less abundant than in positive-mode MALDI, EDI, or LDI. Using TTF as a matrix, the most abundant analyte ions produced were radicals or deprotonated anions.
Journal
-
- Journal of the Mass Spectrometry Society of Japan
-
Journal of the Mass Spectrometry Society of Japan 57 (1), 15-22, 2009
The Mass Spectrometry Society of Japan
- Tweet
Keywords
Details 詳細情報について
-
- CRID
- 1390282681473865472
-
- NII Article ID
- 10024837235
-
- NII Book ID
- AN0010555X
-
- ISSN
- 18804225
- 18843271
- 13408097
-
- NDL BIB ID
- 10160508
-
- Text Lang
- ja
-
- Data Source
-
- JaLC
- NDL
- Crossref
- CiNii Articles
- KAKEN
-
- Abstract License Flag
- Disallowed