Model for Solid Electrolyte Gas Electrode Reaction Kinetics; Key Concepts, Basic Model Construction, Extension of Models, New Experimental Techniques for Model Confirmation, and Future Prospects
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- MIZUSAKI Junichiro
- Tohoku University Atelier Mizusaki
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In order to survey history and state of art of theoretical and kinetic studies of gas electrode reaction on solid oxide electrolyte, overview was made on the research works reported by the author and his co-investigators. Through reviewing their works, frontier of research is clarified. It was shown that electrode reaction is controlled by non-faradaic chemical reaction process, and the nature of the overpotential is the chemical potential deviation of the interface from equilibrium state. Mechanical stress at the electrode/solid electrolyte interface is considered varying with the overpotential. Importance is emphasized for mechano-electrochemistry, the field to study the relationship of electrochemistry and mechanical property of the electrochemical cells.
収録刊行物
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- Electrochemistry
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Electrochemistry 82 (10), 819-829, 2014
公益社団法人 電気化学会
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詳細情報 詳細情報について
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- CRID
- 1390282681474695168
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- NII論文ID
- 130004697474
- 40020212618
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- NII書誌ID
- AN00151637
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- ISSN
- 21862451
- 13443542
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- NDL書誌ID
- 025815608
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用可