Improvement of Cathode Properties by Lithium Excess in Disordered Rocksalt Li<sub>2+2</sub><i><sub>x</sub></i>Mn<sub>1−</sub><i><sub>x</sub></i>Ti<sub>1−</sub><i><sub>x</sub></i>O<sub>4</sub>

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  • Improvement of Cathode Properties by Lithium Excess in Disordered Rocksalt Li₂₊₂xMn₁₋xTi₁₋xO₄
  • Improvement of Cathode Properties by Lithium Excess in Disordered Rocksalt Li<sub>2+2</sub><i><sub>x</sub></i>Mn<sub>1&minus;</sub><i><sub>x</sub></i>Ti<sub>1&minus;</sub><i><sub>x</sub></i>O<sub>4</sub>

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Abstract

Although Li2MnTiO4 has a large theoretical capacity (295 mAh g−1), the cathode utilization is limited due to the mixed cation occupation in the disordered rocksalt structure. In this study, we have attempted to prepare single-phase Li2+2xMn1−xTi1−xO4 compositions (0 ≤ x ≤ 0.3) with Li excess to further improve the cathode properties of Li2MnTiO4. The rechargeable capacity of the synthesized Li2.4Mn0.8Ti0.8O4 composition was above 220 mAh g−1, which is larger than those of other disordered Li2MTiO4 (M = Ni, Co, Mn and Fe) series. Moreover, the discharge capacity of Li2.4Mn0.8Ti0.8O4 was ca. 190 mAh g−1 after the 15th cycle, and its capacity retention was 82%.

Journal

  • Electrochemistry

    Electrochemistry 84 (8), 597-600, 2016

    The Electrochemical Society of Japan

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