Electro-reductive Halogen-Deuterium Exchange and Methylation of Aryl Halides in Acetonitrile

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  • MITSUDO Koichi
    Division of Chemistry and Biotechnology, Graduate School of Natural Science and Technology, Okayama University
  • OKADA Takahiro
    Division of Chemistry and Biotechnology, Graduate School of Natural Science and Technology, Okayama University
  • SHIMOHARA Shuichi
    Division of Chemistry and Biotechnology, Graduate School of Natural Science and Technology, Okayama University
  • MANDAI Hiroki
    Division of Chemistry and Biotechnology, Graduate School of Natural Science and Technology, Okayama University
  • SUGA Seiji
    Division of Chemistry and Biotechnology, Graduate School of Natural Science and Technology, Okayama University

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Abstract

An electro-reductive halogen-deuterium exchange reaction in CD3CN has been developed. Using 9-fluorenone as a mediator, the electro-reduction of several aryl halides proceeded smoothly to give the deuterated products selectively. A methylation reaction of aryl halides also proceeded under similar conditions.

Journal

  • Electrochemistry

    Electrochemistry 81 (5), 362-364, 2013

    The Electrochemical Society of Japan

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