Cobalt-free Materials for Nickel-metal Hydride Battery: Self-discharge Suppression and Overdischarge-resistance Improvement
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- TAKASAKI Tomoaki
- Research Institute for Ubiquitous Energy Devices, National Institute of Advanced Industrial Science and Technology (AIST)
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- NISHIMURA Kazuya
- GIGACELL Battery Center, Rolling Stock Company, Kawasaki Heavy Industries, Ltd.
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- SAITO Makoto
- Research Institute for Ubiquitous Energy Devices, National Institute of Advanced Industrial Science and Technology (AIST)
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- IWAKI Tsutomu
- Research Institute for Ubiquitous Energy Devices, National Institute of Advanced Industrial Science and Technology (AIST)
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- SAKAI Tetsuo
- Research Institute for Ubiquitous Energy Devices, National Institute of Advanced Industrial Science and Technology (AIST)
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抄録
For use of the large-sized Ni-MH battery in the social-infrastructure, it is important to improve its self-discharge suppression and overdischarge resistance as well as its high-power and long cycle-life performances. The use of the RE0.9Mg0.1Ni3.9Al0.2 alloy as the negative electrode of a Ni-MH battery effectively suppressed the self-discharge compared to the use of the conventional AB5-type alloy. Meanwhile, a carbon-coated Ni(OH)2 prepared using a fluid-bed coating method exhibited a better overdischarge resistance than that using the conventional CoOOH-coated one. The Co, which is an expensive rare metal, is completely removed from the Ni-MH battery using these Co-free electrodes. The Co-free Ni-MH battery combines several good battery characteristics, such as a low self-discharge and overdischarge resistance.
収録刊行物
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- Electrochemistry
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Electrochemistry 81 (7), 553-558, 2013
公益社団法人 電気化学会
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詳細情報 詳細情報について
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- CRID
- 1390282681475913856
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- NII論文ID
- 10031178968
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- NII書誌ID
- AN00151637
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- COI
- 1:CAS:528:DC%2BC3sXht1WmsrvN
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- ISSN
- 21862451
- 13443542
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- NDL書誌ID
- 024669248
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- 本文言語コード
- en
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用可