Polymerization of Vinyl Methyl Ether

DOI
  • Nakano Senji
    Central Research Laboratory, Mitsubishi Chemical Industries

Bibliographic Information

Other Title
  • ビニルメチルエーテルの重合反応の研究

Description

It has already been reported by C. E. Schildknecht that in the cationic polymerization of vinyl ether by using BF3-etherate, there was a limited catalyst concentration, “Threshold value”, under which concentration polymerization never occured. It was found that the threshold value varied with the kind and amount of impurities in the monomer. The catalyst concentration required to initiate the polymerization increases with the affinity of impurities to BF3 and the amount of impurity. From the experimental results, it was proposed that BF3-monomer complex arising from monomer and freed BF3 initiated the polymerization.

Journal

  • Kobunshi Kagaku

    Kobunshi Kagaku 19 (204), 276-280, 1962

    The Society of Polymer Science, Japan

Details 詳細情報について

  • CRID
    1390282681495700352
  • NII Article ID
    130004032314
  • DOI
    10.1295/koron1944.19.276
  • ISSN
    18848079
    00232556
  • Text Lang
    ja
  • Data Source
    • JaLC
    • Crossref
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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