ポリビニルアルコールのモノクロル酢酸化反応の動力学
書誌事項
- タイトル別名
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- Kinetics of Esterification of Polyvinyl Alcohol with Monochloroacetic Acid
説明
Polyvinyl alcohol or its monochloroacetic ester was reacted in the mixtures of monochloroacetic acid and water in the presence of HCl. It was found that an equilibrium existed between esterification and saponification. The same type of the equilibrium relation as that for low molecular monofunctional compounds holds in this case also. The reaction proceeded according to a simple reversible bimolecular reaction scheme. The equilibrium constant and rate constant of the reaction were nearly equal to those for esterification of methanol with monochloroacetic acid. These results support the conclusion deduced in previous reports for the mechanism of saponification of polyvinyl acetate.
収録刊行物
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- 高分子化學
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高分子化學 17 (177), 83-86, 1960
公益社団法人 高分子学会
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詳細情報 詳細情報について
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- CRID
- 1390282681496365184
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- NII論文ID
- 130004032176
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- ISSN
- 18848079
- 00232556
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可
