スチレン, メチルスチレンおよびメトキシスチレンのラジカル重合

DOI

書誌事項

タイトル別名
  • Radical Polymerization of Styrene, <I>p</I>-Methylstyrene and <I>p</I>-Methoxystyrene

説明

To know the relationship between substituents of styrene derivatives and their reactivity in propagation and termination reactions, the elementary reactions in the radical polymerization of p-substituted styrenes were analyzed. In measuring radical life times we used the most proper rotating sector method.<BR>Initiation reaction rate was determined by inhibitor method and in this paper DPPH and benzoquinone were chosen as inhibitor. Obtained kp values of styrene, p-methylstyrene and p-methoxystyrene were 106, 84 and 71, and 2kt values were 10.8×107, 6.6×107 and 3.3×107l/mol·sec, respectively.

収録刊行物

  • 高分子化學

    高分子化學 20 (216), 231-236, 1963

    公益社団法人 高分子学会

詳細情報 詳細情報について

  • CRID
    1390282681496785152
  • NII論文ID
    130004032382
  • DOI
    10.1295/koron1944.20.231
  • ISSN
    18848079
    00232556
  • 本文言語コード
    ja
  • データソース種別
    • JaLC
    • Crossref
    • CiNii Articles
  • 抄録ライセンスフラグ
    使用不可

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