書誌事項
- タイトル別名
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- Syntheses and Polymerization of Various Vinyl Esters
- 公開日
- 1965
- DOI
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- 10.1295/koron1944.22.546
- 公開者
- 公益社団法人 高分子学会
この論文をさがす
説明
Vinyl benzoate (I), vinyl α-naphthoate (II), vinyl triphenylacetate (III), vinyl p-chlorobenzoate (IV), vinyl 2, 4-dichlorobenzoate (V), vinyl hexahydrobenzoate (VI), vinyl trimethylacetate (VII), and vinyl dichloroacetate (VIII) were synthesized mainly by means of transesterification of vinyl acetate with the corresponding carboxylic acids.(V) is a new monomer which melts at 38°C and boils at 105-110°C/4mm Hg. It was found that (IV) boils at 62-69°C/5mm Hg, although 115°C/3mm Hg has been reported as a boiling point of the monomer.<BR>These monomers were polymerized mainly in bulk at 60°C with AIBN as an initiator. While (III) gave no polymer and (II) gave only a small amount of polymer, the other monomers than (II) and (III) were polymerized in high yields. Polymerization rates of (IV), (V), (VI), (VII), and (VIII) were nearly the same one another, but the rate of (I) was considerably lower than those of the others. For the every monomer, molecular weights of obtained polymers increased with increase of conversion, and sometimes insoluble polymers were produced. Some discussions were given for these results.
収録刊行物
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- 高分子化學
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高分子化學 22 (245), 546-551, 1965
公益社団法人 高分子学会
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詳細情報 詳細情報について
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- CRID
- 1390282681497945216
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- NII論文ID
- 130004032552
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- ISSN
- 18848079
- 00232556
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可