書誌事項
- タイトル別名
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- Photosensitive Polymers Having α-Phenylmaleimide Group
- アルファ フェニルマレイミドキ オ モツ カンコウセイ ジュシ
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説明
The photodimerization of α-phenylmaleimides (PMI) was applied to the polymers prepared by the methods shown below so they had PMI groups in the side chains: a) a copolymer of p-aminostyrene was treated with phenylmaleic anhydride, b) polystyrene or poly (benzyl methacrylate) was heated with N-chloromethyl-α-phenylmaleimide (CMPMI) in the presence of zinc chloride, c) a copolymer of maleic anhydride was treated with 2- (α-phenylmaleimido) ethylammonium p-toluene-sulfonate in the presence of triethylamine, and d) poly (vinyl alcohol) was heated with CMPMI in dimethylacetamide. The polymers thus prepared show λmax at 340-345 nm and become insoluble by the irradiation of light of its wavelength shorter than ca. 410 nm. The polymers are highly photosensitive; the sensitivity of the polymer that is modified from poly (benzyl methacrylate) and bearing 10 mol% PMI is approximately equal to that of poly (vinyl cinnamate) sensitized with 5-nitroacenaphthene. Studies were made on the sensitization and the storage stability of the polymers.
収録刊行物
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- 高分子論文集
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高分子論文集 37 (4), 199-206, 1980
公益社団法人 高分子学会
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詳細情報 詳細情報について
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- CRID
- 1390282681498062080
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- NII論文ID
- 130004033896
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- NII書誌ID
- AN00085011
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- ISSN
- 18815685
- 03862186
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- NDL書誌ID
- 2179242
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
- Crossref
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- 抄録ライセンスフラグ
- 使用不可