Polymerization of Vinyl Methacrylate Initiated by Benzenesulfinic Acid.

DOI
  • WATANABE Toshio
    Department of Materials Science and Engineering, Yamagata University
  • YAMAGUCHI Satoshi
    Department of Materials Science and Engineering, Yamagata University
  • SATO Rikiya
    Department of Materials Science and Engineering, Yamagata University
  • TAKEISHI Makoto
    Department of Materials Science and Engineering, Yamagata University

Bibliographic Information

Other Title
  • ベンゼンスルフィン酸によるメタクリル酸ビニルの重合

Abstract

The polymerization of vinyl methacrylate (VMA) with benzenesulfinic acid (BSA) in the presence of 1, 1-diphenyl-2-picrylhydrazyl (DPPH) yielded a soluble linear polymer having vinyl pendants. The polymerization is initiated by nucleophilic addition of BSA to the methacrylic double bond of VMA, and an anionic polymerization proceeds in a manner similar to zwitterion polymerization. Gelation due to crosslinking occurred in the absence of DPPH because of accompanying radical polymerization of the vinyl groups on the polymer chain.

Journal

  • KOBUNSHI RONBUNSHU

    KOBUNSHI RONBUNSHU 54 (5), 362-364, 1997

    The Society of Polymer Science, Japan

Keywords

Details 詳細情報について

  • CRID
    1390282681498204288
  • NII Article ID
    130004035239
  • DOI
    10.1295/koron.54.362
  • ISSN
    18815685
    03862186
  • Text Lang
    ja
  • Data Source
    • JaLC
    • Crossref
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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