The Adsorption Mechanism of 6-Diallylamino-1,3,5-triazine-2,4-dithiol on Iron Surfaces by Conventional Vacuum Deposition.

DOI 2 Citations

Bibliographic Information

Other Title
  • ６‐ジアリルアミノ‐１，３，５‐トリアジン‐２，４‐ジチオール真空蒸着被膜の鉄表面への吸着機構

Abstract

Films of 6-diallylamino-1, 3, 5-triazine-2, 4-dithiol (DA) were formed on iron substrates by the conventional vacuum deposition method. haracteristics of adsorbed DA were investigated using ellipsometry, FTIR-RAS, and XPS to examine the influence of substrates on adsorbed water. The ion substrates were washed with acetone (unbaked substrates), and baked under an ultra high vacuum condition to remove adsorbed water (baked substrates). The results showed that DA mlecules easily adsorbed chemically on the unbaked substrate, by the formation of disulfide, sulfur-carbon, and mercaptide bonds. The reactions of DA on the surface would be predominated by a free radical process. This mechanism was proposed to be originated by radical generation by molecular collision with DA to hydrous ferric oxide (FeOOH) surfaces.

Journal

  • KOBUNSHI RONBUNSHU

    KOBUNSHI RONBUNSHU 60 (3), 108-114, 2003

    The Society of Polymer Science, Japan

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Details 詳細情報について

  • CRID
    1390282681498787712
  • NII Article ID
    130004035595
  • DOI
    10.1295/koron.60.108
  • ISSN
    18815685
    03862186
  • Text Lang
    ja
  • Data Source
    • JaLC
    • Crossref
    • CiNii Articles
  • Abstract License Flag
    Disallowed

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