高結晶性オリゴユニットを構成単位とする弾性高分子鎖の合成と性質
書誌事項
- タイトル別名
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- Synthesis and Properties of Elastic Polymer-Chains Consisting of Highly Crystalline Oligo Units.
抄録
Poly (ε-caprolactone) (PCL) oligomers, prepared from PCL and ethyleneglycol (EG), were allowed to react with 4, 4′-diphenylmethane diisocyanate (MDI) to give PCL-polyaddition products. The crystallinity of the products decreased not only by decreasing the average unit number (n), but also by narrowing the molecular weight distribution (Mw/Mn) of PCL oligomers. The crystallinity required for elastic polymer chains was thus able to be controled by n and Mw/Mn.
収録刊行物
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- 高分子論文集
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高分子論文集 55 (1), 21-25, 1998
公益社団法人 高分子学会
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詳細情報 詳細情報について
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- CRID
- 1390282681499491584
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- NII論文ID
- 130004035263
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- ISSN
- 18815685
- 03862186
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
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- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可