プラズマ反応による銅アセチルアセトナート重合膜の合成と高次構造形成

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  • Preparation of copper acetylacetonate thin films with a higher-ordered structure by plasma polymerization.
  • プラズマ ハンノウ ニ ヨル ドウ アセチルアセトナート ジュウゴウ マク ノ

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Plasma polymerization of copper acetylacetonate (CuAA) was carried out under various conditionsincluding plasma power, plasma duration, monomer as well as substrate temperatures. The films ofpolymeric CuAA thus obtained was colorless transparent or showed a variety of colors such as yellow, green, blue, and red depending on plasma conditions. It was found that the color and appearance of the films aredetermined by the sum total of plasma and thermal energies. The structure and morphology of the filmswere investigated by use of electronic, infrared and X-ray photoelectron spectra as well as transmittanceelectron microscopy, As a result, it was revealed that the films have a higher-ordered structure consisting oforganic and metallic layers.

収録刊行物

  • 高分子論文集

    高分子論文集 44 (4), 267-274, 1987

    公益社団法人 高分子学会

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