高分子フィブリルに関する研究　ＩＩ　　乾式高圧紡出により得られたポリオレフィンフィブリル

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タイトル別名
  • Research of polymer fibrils. II. Polyolefine fibrils obtained from high pressure spinning and their paper-like sheets formed by solvent process.
  • カンシキ コウアツ ボウシュツ ニ ヨリ エラレタ ポリオレフィンフィブリル

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抄録

The production process of microfibrous materials or fibrils in which polyolefinic polymers are spun through an orifice under high temperature and high pressure is called flash spinning. A study was made to determine the high strength fibril producing conditions by dry-spinning a solution of polypropylene in dichloromethane through an orifice at high temperature and high pressure. The water system used in conventional paper forming processes is not applicable in forming a sheet of polyolefine fibrils. In order to develop a solvent system for a sheet forming process capable of dealing with hydrophobic fibrils, a comparative study of various solvents was made to determine how the solvent might facilitate the sheetforming operation. Solvents having solubility parameters near those of polyporpylene promoted the formation of paper-like sheets of fibrils with satisfactory physical properties. We developed new technology for a solvent forming system by modifying a conventional water system so that polypropylene fibrils could be introduced as synthetic pulp.

収録刊行物

  • 高分子論文集

    高分子論文集 44 (7), 523-530, 1987

    公益社団法人 高分子学会

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