Synthesis of plasticized poly(vinyl chloride) powders by gas phase polymerization.

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Other Title
  • 気相重合法による可塑化ポリ塩化ビニルの合成
  • キソウ ジュウゴウホウ ニ ヨル カソカ ポリ エンカ ビニル ノ ゴウセイ

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Abstract

Poly (vinyl choride) powders containing several kinds of plasticizers (di-2-ethylhexyl phthalate, polyester azipate, tricresyl phosphate) were synthesized by gas phase polymerization. For some plasticized PVC systems, the morphology was studied, and the gas phase polymerization was analysed using the χ parameter of the Flory-Huggins theory. The effect of plasticization on the viscoelastic behavior was investigated. The results indicate that Tg (glass transition temperature) of this plasticized PVC was lower than those of PVC blend systems.

Journal

  • KOBUNSHI RONBUNSHU

    KOBUNSHI RONBUNSHU 47 (1), 11-16, 1990

    The Society of Polymer Science, Japan

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