書誌事項
- タイトル別名
-
- Preparation of Phosphorus-Containing Polysuccinimide-Amines
- ガン リンポリコハクサン イミドアミン ノ ゴウセイ
この論文をさがす
抄録
N, N′-Bismaleimido-3, 3′-diphenylalkylphosphine oxide (I) was prepared from bis (3-aminophenyl) -alkylphosphine oxide and maleic anhydride. I and aromatic diamines were used for the synthesis of polysuccinimide-amines containing phosphorus atoms in the main chain. The conditions of the polyaddition and the properties of the resulting polymers were investigated. The polymers were obtained in about 70% yield except in the case of using 4, 4′-diaminodiphenyl sulfone as aromatic diamine. The reduced viscosities of the polymers measured at a concentration of 0.2g/dl in DMA at 30°C were 0.16-0.34. Most of the polymers were soluble in dipolar aprotic solvents, m-cresol, and concd. H2SO4. The reduced viscosity of the polymer in concd. H2SO4 decreased gradually. The phosphorus-containing polysuccinimide-amines had poor thermal stability in comparison with the polyimides having aromatic imide rings such as phosphorus-containing polyamide-imides and polyester-imides. The polymers were self-extinguished immediately when a flame was removed.
収録刊行物
-
- 高分子論文集
-
高分子論文集 36 (12), 803-808, 1979
公益社団法人 高分子学会
- Tweet
キーワード
詳細情報 詳細情報について
-
- CRID
- 1390282681500511360
-
- NII論文ID
- 130004033807
-
- NII書誌ID
- AN00085011
-
- ISSN
- 18815685
- 03862186
-
- NDL書誌ID
- 2071909
-
- 本文言語コード
- ja
-
- データソース種別
-
- JaLC
- NDL
- Crossref
- CiNii Articles
-
- 抄録ライセンスフラグ
- 使用不可