書誌事項
- タイトル別名
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- Polumer Micelles. I. Synthesis and Self-Assembly of Amphiphilic Carbosilane Polymers.
- カルボシラン リョウシンバイセイ ポリマー ノ ゴウセイ ト ジコ ソシキカ
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説明
Synthetic method of amphiphilic polycarbosilanes and their self-assembly in solution or at the air-water interface were investigated. It was found that ring-opening polymerizations of silacyclobutane derivatives were useful techniques to obtain well-defined amphiphilic polycarbosilanes. It was also found that the amphiphilic polymers formed micelles in selective solvents and monolayer films at air-water interface. Topics are (1) living anionic polymerization of 1, 1-dialkylsilacyclobutanes, (2) block copolymer synthesis by means of a living polymerization of 1, 1-diethylsilacyclobutane, (3) small-angle X-Ray scattering (SAXS) analysis of micelles formed by poly (1, 1-diethylsilacyclobutane-block-2-hydroxyethyl methacrylate) in solution, (4) X-Ray reflectivity (XR) analysis of monolayers formed by poly (1, 1-diethylsilacyclobutane-block-2-hydroxyethyl methacrylate) at water surface, (5) synthesis of poly (styrene-block-3-hydroxymethyl-1, 1-dimethylsilacyclobutane) by using polymerization of 3-methylenesilacyclobutane and SAXS analysis of its micelle formation, and (6) synthesis of poly (silacyclobutane-graft-ethylene oxide), and SAXS analysis of its solution behavior.
収録刊行物
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- 高分子論文集
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高分子論文集 58 (4), 161-170, 2001
公益社団法人 高分子学会
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詳細情報 詳細情報について
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- CRID
- 1390282681500683520
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- NII論文ID
- 10006094200
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- NII書誌ID
- AN00085011
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- ISSN
- 18815685
- 03862186
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- NDL書誌ID
- 5752876
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
- Crossref
- CiNii Articles
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- 抄録ライセンスフラグ
- 使用不可
