エステル系有機過酸化物によるスチレン塊状重合の規制とシミュレーション

DOI Web Site

書誌事項

タイトル別名
  • Regulated Bulk Polymerization of Styrene by Ester Group-Containing Peroxides and the Simulation.
  • エステルケイ ユウキ カサンカブツ ニ ヨル スチレン カイジョウ ジュウゴウ

この論文をさがす

抄録

Bulk polymerization of styrene was carried out at 100°C using initiators of ester group-containing peroxides such as t-butylperoxy benzoate, t-butylperoxy isopropyl carbonate, and t-butylperoxy phenyl carbonate which had approximately equal decomposition temperatures, and analyzed by the kinetic method and the simulation to high conversion. The behavior of the polymerization was influenced significantly by the kind of primary radicals with various reactivities. Particularly, the hydrogen atom abstraction from the polymer by the alkoxy radicals and the primary radical termination by stable phenoxy radicals influenced greatly the rates and the molecular weight of the polymer formed in the latter half stage.

収録刊行物

  • 高分子論文集

    高分子論文集 49 (3), 249-257, 1992

    公益社団法人 高分子学会

キーワード

詳細情報 詳細情報について

問題の指摘

ページトップへ