Synthesis of Network Polymers Containing Triazine <i>via</i> Direct Arylation of Fluoroarenes and Their Properties

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  • フルオロアレーンの直接的アリール化による含トリアジンネットワークポリマーの合成とその特性
  • フルオロアレーン ノ チョクセツテキ アリールカ ニ ヨル ガン トリアジンネットワークポリマー ノ ゴウセイ ト ソノ トクセイ

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The direct arylation synthesis of π-conjugated network polymers (conjugated microporous polymers: CMP) containing fluoroarene and triazine moieties was successfully achieved. The direct arylation of 1,2,4,5-tetrafluorobenzene or 1,3,5-trifluorobenzene with a tribromoarene having a triazine core under two reaction conditions (Conditions a: in DMAc, Conditions b: in toluene) gave four types of CMPs (CMP1a, CMP1b, CMP2a and CMP2b). Brunauer-Emmett-Teller (BET) surface area of CMP2a and CMP2b was higher than that of CMP1a and CMP1b because of a higher number of branches. The solvents used for the direct arylation polycondensation thus strongly affected the structure of the resulting CMPs.

Journal

  • KOBUNSHI RONBUNSHU

    KOBUNSHI RONBUNSHU 74 (6), 453-459, 2017

    The Society of Polymer Science, Japan

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