書誌事項
- タイトル別名
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- Experiments on the simultaneous partitioning of divalent metal ions between sphalerite or garnet and 2M aqueous chloride solutions under supercritical conditions
- チョウリンカイ ジョウケン カ ニ オケル センアエンコウ オヨビ ザクロイシ ト 2M エンカブツ スイヨウエキ カン ニ オケル 2カ キンゾク イオン ノ ドウジ ブンパイ ジッケン
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Experiments on the simultaneous partitioning of divalent metal ions were performed in the systems (1) ZnS (sphalerite)−(Ni2+, Co2+, Fe2+, Mn2+, Cd2+)Cl2−H2O and (2) Mn3Al2Si3O12 (spessartine)−(Ni2+, Mg2+, Co2+, Zn2+, Fe2+, Ca2+)Cl2−H2O in the temperature range of 500 to 800°C at 1 kb. In the former system for ion partitioning in the 4-fold coordination, parabola-shaped PC-IR curves with a peak near Zn2+ were obtained and no anomaly was observed for Zn2+ and Ni2+ but Cd2+. In the latter system for ion partitioning in the 8-fold coordination, parabola-shaped PC-IR curves with a peak near Mn2+ were obtained, but Zn2+ deviates from such a trend and tends to concentrate into aqueous chloride solutions. The PC-IR curves for spessartine are gentle compared with those for sphalerite. The PC-IR curves both for spessartine and sphalerite become gentle with increasing temperature.
収録刊行物
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- 岩石鉱物科学
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岩石鉱物科学 33 (4), 151-162, 2004
一般社団法人 日本鉱物科学会
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詳細情報 詳細情報について
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- CRID
- 1390282681502366720
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- NII論文ID
- 10013170385
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- NII書誌ID
- AA1146088X
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- COI
- 1:CAS:528:DC%2BD2cXps1agtrs%3D
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- ISSN
- 13497979
- 1345630X
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- NDL書誌ID
- 7085131
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
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- 使用不可