書誌事項
- タイトル別名
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- Preparation of <i>N</i>-chlorinated Bacterial Cellulose and Its Ultra-Thin Sheet-Making
- N-クロルカ バクテリアセルロース ノ チョウセイ ト ソノ ゴクウス シートカ
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抄録
Preparation of N-chlorinated bacterial cellulose (BC) and its ultra-thin sheet-making were investigated. N-chlorinated BC was prepared by a three step reaction: cyanoethylation, carbamoylethylation and N-chlorination. Cyanoethylated BC of DS (degree of substitution) 0.05 was prepared Michael addition with acrylonitrile at 40°C for about 2.5 h. Carbamoylethylation of cyanoethylated BC readily proceeded by addition of H2O2 at room temperature (20°C) and reached DS 0.05 for about 1 h. In the third step, carbamoylethyleted BC easily reacted with NaClO and gave N-chlorinated BC. The dry tensile index of N-chlorinated BC sheet (10 µm thickness) was about 1.7 times higher than that of a BC sheet, and the wet tensile index was about 3.6 times higher. By N-chlorination of BC, we could prepare sheets down to a thickness of 3 µm. Increasing inter-fiber bond formation of N-chlorinated BC is the reason for improving the sheet-formation.
収録刊行物
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- 高分子論文集
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高分子論文集 70 (2), 50-54, 2013
公益社団法人 高分子学会
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詳細情報 詳細情報について
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- CRID
- 1390282681503409664
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- NII論文ID
- 10031155063
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- NII書誌ID
- AN00085011
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- ISSN
- 18815685
- 03862186
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- NDL書誌ID
- 024294929
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
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- 使用不可