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- TATENO Natsuki
- Division of Earth Evolution Sciences, Graduate School of Life and Environmental Sciences, University of Tsukuba
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- KYONO Atsushi
- Division of Earth Evolution Sciences, Graduate School of Life and Environmental Sciences, University of Tsukuba
書誌事項
- タイトル別名
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- Structural change induced by dehydration in ikaite (CaCO<sub>3</sub>·6H<sub>2</sub>O)
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説明
Dehydration–induced structural change in ikaite, CaCO3·6H2O, is investigated using a low–temperature single–crystal X–ray diffraction study. At −50 °C, the crystal structure of ikaite is monoclinic, of space group C2/c with the unit cell parameters a = 8.8134 (1), b = 8.3108 (1), c = 11.0183 (1) Å, and β = 110.418 (1)°. The measurements were performed in 10 °C steps, revealing a monotonous increase of unit cell volume from 756.3 to 758.0 Å3, up to −20 °C. The unit cell volume then jumps to 771.0 Å3 at −10 °C. The unit cell expands anisotropically along the a–axis followed by the c–axis. The ikaite structure is finally lost at 0 °C, which is a much lower temperature for decomposition than previously reported values. The low temperature decomposition is attributable to the aridity of the sample. The elongation of the O1–O4 intermolecular distance parallel to the (101) plane engenders the substantial increase in the a–axis and c–axis. The two–dimensional molecular sheets composed of the CaCO3·6H2O molecules are stacked with hydrogen bondings along the c–axis. The expansion of the c–axis is affected by variations in the hydrogen bondings between the sheets. The intramolecular Ca–O2 and Ca–O5 bond lengths and the intermolecular O1–O5 distance are greatly elongated immediately before the decomposition of ikaite structure. These expansions along the b–axis, however, are offset by the increase in the O2–C–O2 bond angle in the CO3 geometry, aligned perfectly parallel to the b–axis. The intermolecular angles are maintained as almost constant until the ikaite structure is lost. It can be concluded therefore that the movement of H2O molecules from the crystal lattice occurs simultaneously because the CaCO3·6H2O molecules are stabilized by the hydrogen–bonding network immediately before dehydration.
収録刊行物
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- Journal of Mineralogical and Petrological Sciences
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Journal of Mineralogical and Petrological Sciences 109 (4), 157-168, 2014
一般社団法人 日本鉱物科学会
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詳細情報 詳細情報について
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- CRID
- 1390282681522120704
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- NII論文ID
- 130004678276
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- ISSN
- 13493825
- 13456296
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- 本文言語コード
- en
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- 資料種別
- journal article
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