The partially dehydrated structure of natural heulandite: An in situ high temperature single crystal X-ray diffraction study
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- KHOBAER T.M.
- Institute of Mineralogy, Petrology, and Economic Geology, Faculty of Science, Tohoku University
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- KURIBAYASHI Takahiro
- Institute of Mineralogy, Petrology, and Economic Geology, Faculty of Science, Tohoku University
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- KOMATSU Kazuki
- Institute of Mineralogy, Petrology, and Economic Geology, Faculty of Science, Tohoku University Present address: Centre for Science at Extreme Conditions, The University of Edinburgh
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- KUDOH Yasuhiro
- Institute of Mineralogy, Petrology, and Economic Geology, Faculty of Science, Tohoku University
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説明
In situ high-temperature crystal structure analysis of natural heulandite with the chemical composition (Na1.14K0.40Ca3.64Sr0.21)(Al9.21Si26.88)O72·25.2H2O from Maharastra, India was conducted up to 300 °C. The room-temperature and high-temperature X-ray diffraction intensities of a single crystal were measured using an imaging plate detector coupled with a U-shaped high-temperature furnace. At room temperature, the sample was monoclinic, with C2/m symmetry [a = 17.716(4) Å, b = 17.880(3) Å, c = 7.438(2) Å, and β = 116.43(1)°]. Structural refinement of the data set at room temperature yielded a final R value of R = 0.049 and Rw = 0.115 for 1663 independent reflections. The crystal structures of the partially dehydrated states at elevated temperatures (100 °C, 150 °C, 200 °C, 250 °C and 300°C) were refined using C2/m space group. The loss of H2O and the accompanying migration of cations caused a change in the cell parameters: a- and c-axes and the β angle remained invariant, but the b axis decreased, leading to a reduction of the cell volume. Channels A and B became elongated and compressed, respectively, with increasing degree of dehydration.<br> Dehydration began with the loss of H2O coordinated to the Ca1 site in Channel A, defined by 10-membered tetrahedral rings. At 150 °C, the water coordinated to the Ca1 site was expelled radically, and it caused the Ca1 site to migrate to the cavity wall, forming a stronger bond with a tetrahedral framework, whereas the Ca2 site-coordinated water molecules remained in the 8-membered tetrahedral rings with full occupancy. The loss of water at 250 °C from Channel B triggered a structural change: Part of the structure transformed into a heat-collapsed heulandite structure with new T-O-T connections.
収録刊行物
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- Journal of Mineralogical and Petrological Sciences
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Journal of Mineralogical and Petrological Sciences 103 (2), 61-76, 2008
一般社団法人 日本鉱物科学会
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詳細情報 詳細情報について
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- CRID
- 1390282681522455936
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- NII論文ID
- 10020736940
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- NII書誌ID
- AA11460926
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- ISSN
- 13493825
- 13456296
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- 本文言語コード
- en
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- データソース種別
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- JaLC
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- OpenAIRE
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- 使用不可