Hydration enthalpy for synthetic and cation exchanged A-type zeolites with special reference to zeolite heat pump media.

  • KASAI Toshihiro
    Department of Advanced Materials Science and Engineering, Graduate School of Engineering, Yamaguchi University
  • MAEDA Hiroshi
    Department of Advanced Materials Science and Engineering, Graduate School of Engineering, Yamaguchi University
  • MATSUI Kousuke
    Department of Advanced Materials Science and Engineering, Graduate School of Engineering, Yamaguchi University
  • KURNIA Dewi Fatimah
    Research and Development Centre for Geotechnology Indonesian Institute of Sciences (LIPI)
  • NAKAYAMA Noriaki
    Department of Advanced Materials Science and Engineering, Faculty of Engineering, Yamaguchi University
  • MIZOTA Tadato
    Department of Advanced Materials Science and Engineering, Faculty of Engineering, Yamaguchi University

書誌事項

公開日
1994
DOI
  • 10.2465/minerj.17.170
公開者
一般社団法人 日本鉱物科学会

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説明

Na-A type zeolite has been synthesized from the waste solution with the red mud exhausted from the Bayer process. The heats of water-vapor absorption of the Na–A and cation exchanged zeolites were measured by means of an adiabatic water-vapor absorption calorimeter which had been devised for investigating heat pump effect of zeolites. The integrated hydration enthalpy of A-zeolite is in the same order as those of mordenite and clinoptilolite. However, A-zeolite shows twice the total heat amount obtainable from unit weight samples of a natural zeolite, because natural zeolites contain impurity phases, and their dehydration amount around 100°C is much smaller. Mg-exchanged A-zeolite dehydrated at 100°C showed the largest amount of hydration enthalpy of 65.1kJ/mol, and a weight loss on dehydration of 14.7%. The Mg-A-zeolite will be the most efficient heat pump media of all zeolites dehydrated at 100°C in the present work.

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詳細情報 詳細情報について

  • CRID
    1390282681523064960
  • NII論文ID
    10008771077
    30027161555
  • NII書誌ID
    AA00739590
  • DOI
    10.2465/minerj.17.170
  • ISSN
    18814174
    05442540
    http://id.crossref.org/issn/05442540
  • 本文言語コード
    en
  • データソース種別
    • JaLC
    • Crossref
    • CiNii Articles
    • OpenAIRE
  • 抄録ライセンスフラグ
    使用不可

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