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- 圓藤 紀代司
- 大阪市立大学大学院工学研究科
書誌事項
- タイトル別名
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- Synthesis of Polycatenane by Polymerization of Cyclic Disulfides and Shape-Memory Characteristics of the Polymer
- カンジョウ ジスルフィド ノ ジュウゴウ ニ ヨル ポリカテナン ノ ゴウセイ ト ケイジョウ キオク トクセイ
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This review describes thermal polymerization of cyclic disulfides without any initiators. Cyclic disulfides such as 1, 2-dithiane (DT) and 1, 4-dihydro-2, 3-benzodithine (XDS) can polymerize easily at reaction temperature of the melting points of the respective monomers to give a high molecular weight polymer determined by GPC. From the analyses of NMR and ESI-MS spectroscopies, the polymers obtained from the polymerization of cyclic disulfides were found to be a cyclic structure. Moreover, thermal and mechanical properties of the polymers, and decomposition behaviors of the polymers demonstrate that the polymers obtained from thermal polymerization of cyclic disulfides include a polycatenane structure. From polymerization of cyclic disulfides in the presence of cyclic poly (ethylene oxide), a polycatenane consisting of two different cyclic polymer was obtained. The polymers revealed characteristics as a shape-memory material.
収録刊行物
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- 日本ゴム協会誌
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日本ゴム協会誌 80 (5), 191-196, 2007
一般社団法人 日本ゴム協会
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詳細情報 詳細情報について
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- CRID
- 1390282681537956224
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- NII論文ID
- 10018616705
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- NII書誌ID
- AN00269207
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- ISSN
- 18840442
- 0029022X
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- NDL書誌ID
- 8820595
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- 本文言語コード
- ja
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- データソース種別
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- JaLC
- NDL
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- 抄録ライセンスフラグ
- 使用不可