高圧水素ガス環境下におけるエチレンプロピレンゴム製シール材の破壊現象と水素透過特性

  • 山辺 純一郎
    九州大学水素エネルギー国際研究センター 独)産業技術総合研究所水素材料先端科学研究センター
  • 古賀 敦
    NOK株式会社
  • 西村 伸
    独)産業技術総合研究所水素材料先端科学研究センター 九州大学大学院工学研究院機械工学部門

書誌事項

タイトル別名
  • Fracture Behavior and Hydrogen Permeation Properties of EPDM for Sealing under High Pressure Hydrogen Gas
  • コウアツ スイソ ガス カンキョウ カ ニ オケル エチレンプロピレンゴムセイ シールザイ ノ ハカイ ゲンショウ ト スイソ トウカ トクセイ

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抄録

In order to evaluate the influence of environmental condition on durability and permeation properties of sealing rubber materials under high pressure hydrogen gas, a durability tester which enables the sealing rubber to expose repeatedly high pressure hydrogen gas at arbitrary test conditions (maximum pressure is 90 MPa and the range of ambient temperature is from –60 to 100 °C) was developed. In this study, durability and hydrogen permeation properties of peroxide- vulcanized EPDM composite filled with white reinforcing filler were evaluated under hydrogen gas at a maximum pressure of 70 MPa and the range of ambient temperature from 0 to 100 °C. The dependence of the ambient temperature on permeability, diffusivity, and solubility was not influenced by the hydrogen pressure and the shape of specimen. Moreover, although we can regard that hydrogen content was approximately proportional to the hydrogen pressure at ≤10 MPa, this relationship became non-linear when a hydrogen pressure became higher. As for durability, blister damage became more serious with an increase in the hydrogen pressure and ambient temperature. Furthermore, damage by extrusion was also observed at ≥35 MPa due to large gas absorption.

収録刊行物

  • 日本ゴム協会誌

    日本ゴム協会誌 83 (6), 159-166, 2010

    一般社団法人 日本ゴム協会

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